[Philip Lelyveld comment; there is a long story in today's (8/4/13) LA Times about The Canyons, an ultra low budget legitimate movie staring James Deen and Lindsey Lohan written by Brett Easton Ellis.]
Given that Glass has been in the wild for some time, we're extremely doubtful this is the first X-rated video made with it. It is, however, the first professionally-made one we're aware of, especially with breakout star Deen involved. The glasses themselves were apparently obtained from Motherboard's Arikia Millikan, who attended the shooting, and adult app company MiKandi — whose first attempt at working with Glass was abruptly stymied when Google pulled its "Tits and Glass" app after only a few hours.
... as the scene progressed, Glass itself started to heat up. That's not innuendo. That's what happens when you record for too long.
Here is the link to the censored version of the trailer; http://www.youtube.com/watch?v=Xxt24JoLlPE
Read the full story here: http://www.theverge.com/2013/7/23/4549416/id-tap-that-glass-james-deen-releases-first-google-glass-porno